The Composition and Morphology Evolution of Oxide Inclusions in Ti-bearing Ultra Low-carbon Steel Melt Refined in the RH Process

被引:55
|
作者
Wang, Min [1 ]
Bao, Yan-ping [1 ]
Cui, Heng [1 ]
Wu, Hua-jie [1 ]
Wu, Wei-shuang [1 ]
机构
[1] Univ Sci & Technol Beijing, Engn Res Inst, Engn Res Ctr Met Technol, Beijing 100083, Peoples R China
关键词
deoxidation; inclusion; ultra low-carbon steel; morphology of Al2O3 center dot TiOx complex oxide; Al2O3; cluster; AL-TI; THERMODYNAMIC ANALYSIS; BEHAVIOR; SYSTEM; MODEL; FLOW;
D O I
10.2355/isijinternational.50.1606
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Before deoxidation, the main inclusions were Fe-Mn-O inclusions in Ti-bearing ultra low-carbon steel melt. After 3 min Al addition, the inclusions changed to be granular and spherical Al2O3 center dot Al2O3 cluster, composed of granular and spherical particles with diameter 1-2 mu m, formed in 7 to 10 min after Al addition into the melt. Al2O3 center dot TiOx inclusions with the Ti/(Al+Ti) between 0.15 and 0.30 formed 3 min after ferro-titanium addition and Al2O3 center dot TiOx cluster formed because rich [Ti] and poor [Al] regions existed around the ferro-titanium particles and Al2O3 cluster. The Ti3O5 was hard to be formed when acid-soluble aluminum exceeded 0.035% with titanium blow 0.08%. The activity of Ti3O5 in the complex liquid phase inclusions increased remarkably with the decrease of acid-soluble aluminum and increase of titanium.
引用
收藏
页码:1606 / 1611
页数:6
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