Liquid-Liquid Phase Transition in Aqueous Solutions of n-Hydrocarbons and Amphiphiles

被引:5
|
作者
Mirgorod, Yu. A. [1 ]
机构
[1] Kursk State Tech Univ, Kursk 305040, Russia
关键词
THERMODYNAMIC ANALYSIS;
D O I
10.1134/S1063785010100068
中图分类号
O59 [应用物理学];
学科分类号
摘要
Phase transitions in ensembles of water clusters in aqueous solutions of C11-C28 n-hydrocarbons and C2-C12 amphiphiles have been studied as dependent on the concentration and size of dissolved molecules. A critical size (approximately corresponding to the volume of undecane molecule) for water clusters is determined, which triggers the phase transition that leads to the formation of bistable amphiphile micelles.
引用
收藏
页码:892 / 894
页数:3
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