Energy-Intensive Random Block Copolymers of 3,3-Bis (Nitratomethyl) Oxetane and 3-Azidomethyl-3-Methyloxetane

被引：2
|
作者：
Mukhametshin, Timur I. [1 ]
Sharipov, Rail I. [1 ]
Petrov, Vladimir A. [1 ]
Kostochko, Anatoly V. [1 ]
Vinogradov, Dmitry B. [2 ]
Bulatov, Pavel V. [2 ]
机构：
[1] Inst Kazan Natl Res Technol Univ, Dept Chem & Technol Macromol Cpds, Karl Marx Str 68, Kazan 420015, Russia
[2] Russian Acad Sci, Inst ND Zelinsky Inst Organ Chem, Leninsky Prospect 47, Moscow 119334, Russia
来源：
PROPELLANTS EXPLOSIVES PYROTECHNICS | 2018年 / 43卷 / 11期
关键词：
3,3-bis (nitratomethyl) oxetane; 3-azidomethyl-3-methyloxetane; triisobutylaluminum; energy-intensive copolymers; POLY(3-AZIDOMETHYL-3-METHYL OXETANE); SUBSTITUTED OXETANES; ORGANIC NITRATES; AZIDO POLYMERS; POLYMERIZATION;
D O I：
10.1002/prep.201800216
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Copolymerization of 3,3-bis (nitratomethyl) oxetane and 3-azidomethyl-3-methyloxetane was carried out in the presence of the triisobutyl-aluminum-water catalyst system. The structure of synthesized high-molecular copolymers was proven with C-13 and H-1 NMR, IR-Fourier spectroscopy, GPC, and elemental analysis. The data on relaxation and phase transitions as well as the thermal decomposition of copolymers were obtained using the DSC method.
引用
收藏
页码：1115 / 1121
页数：7
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