Radical terpolymerization of acrylamide, acrylic acid and N-(1,1-dimethyl-3-oxobutyl) acrylamide

被引：2
|
作者：
Camail, M [1 ]
Essaoudi, H [1 ]
Gedoux, B [1 ]
Margaillan, A [1 ]
Vernet, JL [1 ]
机构：
[1] Univ Toulon & Var, Inst Sci Ingn, Lab Chim Appl, F-83957 La Garde, France
来源：
EUROPEAN POLYMER JOURNAL | 1998年 / 34卷 / 07期
关键词：
D O I：
10.1016/S0014-3057(97)00221-8
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis of terpolymers from acrylamide (AM, monomer 1), acrylic acid (AA, monomer 2) and N-(1,1-dimethyl 3-oxobutyl) acrylamide (DAAM, monomer 3) has been carried out in a water solution, at 30 degrees C using K2S2O4 as an initiator. The characterization of terpolymers has been obtained through H-1 NMR, microanalysis and gel permeation chromatography. Radical copolymerization of AM/AA, AM/DAAM and AA/DAAM were carried out in the same way as the terpolymerization described. The reactivity ratios for those couples have been assessed and are respectively r(12) = 0.63; r(21) = 1.43; r(13) = 1.07; r(31) = 0.54; r(23) = 1.46; r(32) = 9.32. Those values enable to foresee the monomer compositions into terpolymers. The composition range allowing to obtain polymers both soluble in waterand organic solvents has been identified. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1007 / 1012
页数：6
相关论文
共 50 条
  • [1] RADICAL COPOLYMERIZATION OF N-(1,1-DIMETHYL-3-OXOBUTYL)-ACRYLAMIDE IN DIFFERENT SOLVENTS
    FRANCO, S
    LEONI, A
    POLYMER, 1973, 14 (01) : 2 - 4
  • [2] SYNTHESIS AND PROPERTIES OF POLY[N-(1,1-DIMETHYL-3-OXOBUTYL)ACRYLAMIDE OXIME]
    TAYLOR, LD
    KOLESINSKI, HS
    RICKTER, DO
    GRASSHOFF, JM
    DEMEMBER, JR
    MACROMOLECULES, 1983, 16 (10) : 1561 - 1563
  • [3] INTENSITY DEPENDENCE OF GAMMA-RADIATION-INDUCED POLYMERIZATION OF SOLID N-(1,1-DIMETHYL-3-OXOBUTYL)-ACRYLAMIDE (DIACETONE ACRYLAMIDE)
    LIPSCOMB, NT
    PURCELL, TO
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1971, 9 (11): : 831 - &
  • [4] WATER-SOLUBLE COPOLYMERS .24. COPOLYMERS OF ACRYLAMIDE WITH N-(1,1-DIMETHYL-3-OXOBUTYL)-N-(N-PROPYL)ACRYLAMIDE - SOLUTION PROPERTIES
    MCCORMICK, CL
    BLACKMON, KP
    ELLIOTT, DL
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1986, 144 : 87 - 99
  • [5] WATER-SOLUBLE COPOLYMERS .23. COPOLYMERS OF ACRYLAMIDE WITH N-(1,1-DIMETHYL-3-OXOBUTYL)-N-(N-PROPYL)ACRYLAMIDE - SYNTHESIS AND CHARACTERIZATION
    MCCORMICK, CL
    BLACKMON, KP
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1986, 144 : 73 - 86
  • [6] Synthesis and Characterization of a Novel Thermosensitive Poly(acrylamide-co-N(1,1-Dimethyl-3-oxobutyl)-Acrylamide) Hydrogel
    Wang, Yu
    Xia, Huifang
    Liu, Jiuhui
    2016 INTERNATIONAL CONFERENCE ON MATERIAL, ENERGY AND ENVIRONMENT ENGINEERING (ICM3E 2016), 2016, : 78 - 84
  • [7] Solubilization of hibitane with fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomers.
    Sawada, H
    Murai, Y
    Yanagida, K
    Nishikawa, Y
    Kawase, T
    Oharu, K
    Nakagawa, H
    Ohira, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U548 - U548
  • [8] Solubilization of phthalocyanines into methanol with fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)and N,N-dimethyl-acrylamide oligomers
    Sasazawa, K
    Okitsu, I
    Aburatani, A
    Kawase, T
    Sawada, H
    JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 93 (02) : 521 - 525
  • [9] Arrangement of fullerene above the poly(methyl methacrylate) surface with fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide polymers
    Sawada, H
    Lidzuka, J
    Kawase, T
    Oharu, K
    Nakagawa, H
    EUROPEAN POLYMER JOURNAL, 2003, 39 (10) : 1991 - 1993
  • [10] SYNTHESIS OF N-(1,1-DIMETHYL-3-OXOBUTYL)-2-OXOCYCLOALKANE CARBOTHIOAMIDES
    SINGH, H
    SINGH, S
    MEHTA, RK
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1976, 14 (08): : 615 - 616
12345