Iron-catalyzed aerobic oxidative phosphonation of N-aryl tetrahydroisoquinolines

被引：7
|
作者：
Cai, Junjie [1 ]
Liu, Yingle [1 ]
Jiang, Yan [1 ]
Yang, Yi [1 ]
机构：
[1] Sichuan Univ Sci & Engn, Coll Chem & Environm Engn, Key Lab Green Catalysis Higher Educ Inst Sichuan, 180 Xueyuan St,Huixing Rd, Zigong 643000, Sichuan, Peoples R China
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2017年 / 192卷 / 09期
基金：
中国国家自然科学基金;
关键词：
Oxidative phosphonation; iron catalysis; coupling; alpha-aminophosphonate; DEHYDROGENATIVE-COUPLING REACTIONS; C-H FUNCTIONALIZATION; BOND-FORMING REACTIONS; TERTIARY-AMINES; ALPHA-AMINOPHOSPHONATES; BIOLOGICAL-PROPERTIES; ANTITUMOR-ACTIVITY; ACID-DERIVATIVES; EFFICIENT; INHIBITORS;
D O I：
10.1080/10426507.2017.1330827
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We report herein a novel and efficient method for iron-catalyzed aerobic oxidative phosphonation of N-aryl tetrahydroisoquinolines for the synthesis of biologically interesting alpha-aminophosphonates. This new C-P bond formation reaction features the employment of a sustainable and cost-effective iron salt [Fe(NO3)(3)center dot 9H(2)O] as catalyst, the utilization of air as environmental-benign oxidant, as well as the user-friendly open-flask reaction conditions.
引用
收藏
页码：1068 / 1073
页数：6
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