A modified tank in series model for cogeneration of hydroxylamine and electricity in the nitric oxide/hydrogen fuel cell

被引：4
|
作者：
Danilov, Valery A. [2 ]
Denayer, Joeri F. M. [1 ]
机构：
[1] Vrije Univ Brussel, Dept Chem Engn CHIS, B-1050 Brussels, Elsene, Belgium
[2] Kazan State Technol Univ, Dept Proc & Unit Operat Chem Technol, Kazan 420015, Russia
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2012年 / 37卷 / 12期
关键词：
Hydroxylarnine; Nitric oxide; Fuel cell; Current efficiency; OXIDE REDUCTION; OXIDATION; REACTOR;
D O I：
10.1016/j.ijhydene.2012.03.106
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This work presents a modified TSR model of the nitric oxide/hydrogen fuel cell operating in potentiostatic mode with the co-current flow direction. The developed model accounts for the component and the energy balances in gas channels, liquid catholyte and catalyst layers together with charge balances at electrode/electrolyte interfaces. The simulation results indicate the influence of catalyst selectivity and mass transfer on the distribution of concentration, temperature and current density. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：9863 / 9872
页数：10
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