Changing the gold standard

被引：7
|
作者：
Bourissou, Didier [1 ]
机构：
[1] Univ Toulouse, CNRS, Lab Heterochim Fondamentale & Appl, Toulouse, France
来源：
NATURE CHEMISTRY | 2019年 / 11卷 / 03期
关键词：
COMPLEXES;
D O I：
10.1038/s41557-019-0223-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Gold — long presumed to be an inert metal — has been increasingly shaking this image over the past couple of decades, mostly through electrophilic behaviour. Now, a two-coordinate gold complex has been shown to exhibit nucleophilic reactivity, with the insertion of CO2 into its polarized Auδ−–Alδ+ bond.
引用
收藏
页码：199 / 200
页数：2
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