Bis(μ-di-2-pyridylaminato 1-oxide)bis[(trifluoroacetato)copper(II)] acetonitrile disolvate

被引：2
|
作者：
Zeng, XR [1 ]
Fang, XN
Peng, SM
Lin, HM
机构：
[1] JiangGangShan Normal Coll, Dept Chem, Jian 343009, Jiangxi, Peoples R China
[2] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan
[3] Acad Sinica, Inst Chem, Taipei, Taiwan
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2003年 / 59卷
关键词：
D O I：
10.1107/S010827010302064X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of the title compound, [Cu-2(C2F3O2)(2)-(C10H8N3O)(2)].2CH(3)CN, contains discrete [Cu-2(CF3COO)(2)-(O-dpa)(2)] molecules (O-dpaH is di-2-pyridylamine 1-oxide) which have imposed crystallographic twofold symmetry and an acetonitrile molecule of solvation. The O-dpa(-) ligand is both bidentate and bridging, linking two Cu atoms with a separation of 3.4270 (11) Angstrom. Each Cu atom is surrounded by four coordinated atoms that are almost coplanar, with dimensions Cu-N = 1.940 (2) and 1.984 (3) Angstrom, and Cu-O = 1.912 (2) and 1.945 (2) Angstrom.
引用
收藏
页码：M497 / M498
页数：2
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