Bis(μ-di-2-pyridylaminato 1-oxide)bis[(trifluoroacetato)copper(II)] acetonitrile disolvate

被引：2
|
作者：
Zeng, XR [1 ]
Fang, XN
Peng, SM
Lin, HM
机构：
[1] JiangGangShan Normal Coll, Dept Chem, Jian 343009, Jiangxi, Peoples R China
[2] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan
[3] Acad Sinica, Inst Chem, Taipei, Taiwan
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2003年 / 59卷
关键词：
D O I：
10.1107/S010827010302064X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of the title compound, [Cu-2(C2F3O2)(2)-(C10H8N3O)(2)].2CH(3)CN, contains discrete [Cu-2(CF3COO)(2)-(O-dpa)(2)] molecules (O-dpaH is di-2-pyridylamine 1-oxide) which have imposed crystallographic twofold symmetry and an acetonitrile molecule of solvation. The O-dpa(-) ligand is both bidentate and bridging, linking two Cu atoms with a separation of 3.4270 (11) Angstrom. Each Cu atom is surrounded by four coordinated atoms that are almost coplanar, with dimensions Cu-N = 1.940 (2) and 1.984 (3) Angstrom, and Cu-O = 1.912 (2) and 1.945 (2) Angstrom.
引用
收藏
页码：M497 / M498
页数：2
相关论文
共 50 条
  • [1] Bis[chloridobis(triphenylphosphine)copper(I)-μ-chlorido]bis(1,2-diaminopropane)copper(II) acetonitrile disolvate
    Habibi, Mohammad Hossein
    Mikhak, Maryam
    Harrington, Ross W.
    Clegg, William
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M2305 - U544
  • [2] Poly[[bis(acetonitrile-κN)bis{μ-2-[(2-carboxylatoethyl)ammoniomethyl] benzoato}copper(II)]bis(perchlorate) acetonitrile disolvate]
    Musie, Ghezai T.
    Li, Xiaobao
    Klausmeyer, Kevin K.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1966 - M1968
  • [3] Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate
    Watton, Stephen P.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M585 - U1081
  • [4] BIS[2-(METHYLAMINOMETHYL)PYRIDINE 1-OXIDE]COPPER(II) DIPERCHLORATE
    PAVKOVIC, SF
    BROWN, JN
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (JAN): : 274 - 276
  • [5] BIS-(2-DIMETHYLAMINOPYRIDINE 1-OXIDE)COPPER(II) DIPERCHLORATE
    WEST, DX
    PAVKOVIC, SF
    BROWN, JN
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (JAN): : 143 - 145
  • [6] BIS[MU-(2-METHYLAMINOPYRIDINE 1-OXIDE)-MU-O]-BIS[DICHLORO(2-METHYLAMINOPYRIDINE 1-OXIDE)COPPER(II)]
    PAVKOVIC, SF
    WILLE, SL
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (MAY): : 1605 - 1607
  • [7] trans-bis(ethylenediamine)bis(trifluoroacetato)copper(iI)
    Karpova, Elena V.
    Zakharov, Maxim A.
    Gutnikov, Sergey I.
    Boltalin, Alexandr I.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : m658 - m659
  • [8] Bis[bis(3-phenylpyrazol-l-yl)(pyrazol-1-yl)methane] copper(II) bis(perchlorate) acetonitrile disolvate
    Goodman, MS
    Goodman, MA
    Kovalevsky, AY
    Nazarenko, AY
    Pope, DA
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2006, 62 (02): : M30 - M32
  • [9] Bis[bis(methoxycarbimido)aminato]copper(II) 1-methylpyrrolidin-2-one disolvate
    Chippindale, Ann M.
    Bilbe, Edward J.
    Hibble, Simon J.
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2009, 65 : M485 - M487
  • [10] Di-μ-chloro-bis[diacetonitriledichloroniobium(III)] acetonitrile disolvate
    Kakeya, M
    Fujihara, T
    Nagasawa, A
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M893 - M894
12345