Sn-based intermetallic materials performances and mechanisms

被引：44
|
作者：
Naille, S. [1 ]
Ionica-Bousquet, C. M. [1 ]
Robert, F. [1 ]
Morato, F. [1 ]
Lippens, P-E. [1 ]
Olivier-Fourcade, J. [1 ]
机构：
[1] Univ Montpellier 2, CNRS, UMR 5072, Lab Agregats Mol & Mat Inorgan, F-34095 Montpellier 5, France
来源：
JOURNAL OF POWER SOURCES | 2007年 / 174卷 / 02期
关键词：
Sn-based intermetallic compounds; lithium-ion batteries; Sn-119 Mossbauer spectroscopy;
D O I：
10.1016/j.jpowsour.2007.06.040
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ni3Sn4 and CoSn2 which are two Sn-based intermetallic compounds with different crystal structures have been tested as future negative electrodes for lithium-ion batteries. Various two-step reactions occur during the first discharge of these two electrodes. The first discharge shows good specific capacities: 515 mAh g(-1) for the Ni3Sn4 electrode and 606 mAh g(-1) for the CoSn2 electrode. These reactions lead to the formation of Li7Sn2, a Li-rich LixSn alloy characterized by Sn-119 Mossbauer spectroscopy. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：1091 / 1094
页数：4
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