Superelectrophilic Diels-Alder reactions and oxidations leading to heterocyclic biaryl compounds

被引：5
|
作者：
Hien Vuong [1 ]
Klumpp, Douglas A. [1 ]
机构：
[1] Northern Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA
来源：
SYNTHETIC COMMUNICATIONS | 2019年 / 49卷 / 02期
基金：
美国国家科学基金会;
关键词：
Biaryl; heterocycle; superacid; oxidation; C-H ARYLATION; COMPLEXES;
D O I：
10.1080/00397911.2018.1554149
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Heterocyclic imines provide biaryl products by a two-step transformation. The first transformation involves a Diels-Alder reaction with a multiply protonated imine to give a tetrahydroquinoline product, whereas the second step involves oxidation with elemental sulfur at 260 degrees C. [GRAPHICS]
引用
收藏
页码：316 / 323
页数：8
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