Activity coefficient derivatives of ternary systems based on Scatchard's neutral electrolyte description

被引：11

作者：

Miller, Donald G. ^{[1
]}

机构：

[1] Lawrence Livermore Natl Lab, Energy & Environm Directorate, Livermore, CA 94551 USA

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2008年 / 37卷 / 03期

关键词：

ternary system; Scatchard Neutral Electrolyte description; activity coefficient derivatives; binary approximations; binary evaluation strategies;

D O I：

10.1007/s10953-007-9236-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Activity coefficient derivatives with respect to molality are presented for the Scatchard Neutral Electrolyte description of a ternary common-ion electrolyte system. These quantities are needed for the calculation of "diffusion Onsager coefficients" and in turn for tests of the Onsager Reciprocal Relations in diffusion. The usually-omitted b(23) term is included. The direct SNE binary approximations and a further approximation are discussed. Binary evaluation strategies other than constant ionic strength are considered.

引用

页码：365 / 375

页数：11

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