Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids

被引：131
|
作者：
Li, Shen [1 ]
Zhu, Shou-Fei [1 ]
Zhang, Can-Ming [1 ]
Song, Song [1 ]
Zhou, Qi-Lin [1 ]
机构：
[1] Nankai Univ, State Key Lab, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 27期
关键词：
D O I：
10.1021/ja802399v
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly efficient iridium-catalyzed hydrogenation of alpha,beta-unsaturated carboxylic acids has been developed by using chiral spiro-phosphino-oxazoline ligands, affording a-substituted chiral carboxylic acids in exceptionally high enantioselectivities and reactivities.
引用
收藏
页码：8584 / +
页数：3
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