X-ray structural study of Li3N at high pressure

被引：0
|
作者：
Ho, AC [1 ]
Granger, MK [1 ]
Ruoff, AL [1 ]
机构：
[1] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA
来源：
HIGH-PRESSURE MATERIALS RESEARCH | 1998年 / 499卷
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The equation of state (EOS) of Li3N has been determined by energy-dispersive x-ray diffraction (EDXD) using synchrotron radiation up to 35 GPa at ambient temperature. Both the hexagonal D-6h(4)(P6(3)/mmc) and the hexagonal D-6h(1)(P6/mmm) phases were present at ambient pressure. The D-6h(1)-structure completely transforms into the D-6h(4)-structure at modest pressure. The change in Gibb's free energy as a function of pressure for Li3N was calculated using the experimental EOS.
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页码：133 / 138
页数：6
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