Pd-Catalyzed Direct C-H Bond Sulfonylation of Azobenzenes with Arylsulfonyl Chlorides

被引：94
|
作者：
Zhang, Duo [1 ]
Cui, Xiuling [1 ,2 ,3 ]
Zhang, Qianqian [1 ]
Wu, Yangjie [1 ]
机构：
[1] Zhengzhou Univ, Henan Key Lab Chem Biol & Organ Chem, Key Lab Appl Chem Henan Univ, Dept Chem, Zhengzhou 450052, Peoples R China
[2] Huaqiao Univ, Inst Mol Med, Sch Biomed Sci, Xiamen Key Lab Ocean & Gene Drugs, Xiamen 361021, Fujian, Peoples R China
[3] Chinese Educ Minist, Engn Res Ctr Mol Med, Xiamen 361021, Fujian, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 03期
基金：
中国国家自然科学基金;
关键词：
HETEROCYCLIC AZO DYESTUFFS; ANALYTICAL-CHEMISTRY; EFFICIENT SYNTHESIS; HUMAN ANGIOGENIN; ORTHO-ACYLATION; SULFONES; ARYL; INHIBITORS; ARYLATION; OXIDATION;
D O I：
10.1021/jo502451k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Pd(II)-catalyzed C-H sulfonylation of azobenzenes with arylsulfonyl chlorides has been developed. The sulfonylazobenzenes were obtained in moderate to excellent yields for 28 examples. This protocol features high efficiency, wide functional group tolerance, and atom economy.
引用
收藏
页码：1517 / 1522
页数：6
相关论文
共 50 条
  • [21] N-Heterocyclic Carbene Dichotomy in Pd-Catalyzed Acylation of Aryl Chlorides via C-H Bond Functionalization
    Flores-Gaspar, Areli
    Gutierrez-Bonet, Alvaro
    Martin, Ruben
    ORGANIC LETTERS, 2012, 14 (20) : 5234 - 5237
  • [22] Pd-catalyzed, nondirected C-H aminations
    Emmert, Marion H.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [23] Pd-catalyzed silylation of alkenes via allylic C-H bond functionalization
    Zhao, Tony S. N.
    Larsson, Johanna M.
    Szabo, Kalman J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [24] Pd-Catalyzed Direct C-H Activation for the C5-Olefination of Methyleneindolinones
    Xu, Xian-Kuan
    Liu, Jian-Wei
    Li, Deng-Yuan
    Liu, Pei-Nian
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (10): : 7288 - 7295
  • [25] Pd-Catalyzed C-3 functionalization of indolizines via C-H bond cleavage
    Zhao, Baoli
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (35) : 7108 - 7119
  • [26] Pd-catalyzed double C-H bond activation of diaryl ketones for the synthesis of fluorenones
    Gandeepan, Parthasarathy
    Hung, Chen-Hsun
    Cheng, Chien-Hong
    CHEMICAL COMMUNICATIONS, 2012, 48 (75) : 9379 - 9381
  • [27] Pd-Catalyzed Chlorodifluoroethylation Reaction of C-H Bond of Acetanilides with Chlorodifluoroethyl Iodonium Reagents
    Cao, Chengyao Kimmy
    Niu Yaru
    Jiang Yunchen
    Qu Hongmei
    Chen Chao
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2022, 42 (07) : 2098 - 2105
  • [28] Access to Isothiazolones from Simple Acrylamides by Pd-Catalyzed C-H Bond Activation
    Chen, Mu-Yi
    Pannecoucke, Xavier
    Jubault, Philippe
    Besset, Tatiana
    JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (20): : 13194 - 13202
  • [29] Electrochemical Methods for Pd-catalyzed C-H Functionalization
    Erchinger, Johannes E.
    van Gemmeren, Manuel
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 10 (01) : 50 - 60
  • [30] Pd-Catalyzed C-H Silylation Reactions with Disilanes
    Zhou, Bo
    Lu, Ailan
    Zhang, Yanghui
    SYNLETT, 2019, 30 (06) : 685 - 693
12345