NaBH4/NaHSO4•H2O a heterogeneous acidic system for a mild and convenient reduction of carbonyl compounds under protic condition

被引：10
|
作者：
Zeynizadeh, B [1 ]
Behyar, T [1 ]
机构：
[1] Urmia Univ, Fac Sci, Dept Chem, Urmia 57159165, Iran
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2005年 / 60卷 / 04期
关键词：
borohydride reduction; sodium bisulfate; carbonyl compounds;
D O I：
10.1515/znb-2005-0417
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
NaBH4 in the presence of sodium bisulfate (NaHSO(4)center dot H2O), a weakly acidic reagent, efficiently reduces a variety of carbonyl compounds such as aldehydes, ketones, alpha, beta-unsaturated aldehydes and ketones, alpha-diketones and acyloins to their corresponding alcohols in acetonitrile under heterogeneous condition. Reduction reactions were accomplished at room temperature or under reflux condition.
引用
收藏
页码：453 / 457
页数：5
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