NaBH4/NaHSO4•H2O a heterogeneous acidic system for a mild and convenient reduction of carbonyl compounds under protic condition

被引：10

作者：

Zeynizadeh, B ^{[1
]}

Behyar, T ^{[1
]}

机构：

[1] Urmia Univ, Fac Sci, Dept Chem, Urmia 57159165, Iran

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2005年 / 60卷 / 04期

关键词：

borohydride reduction; sodium bisulfate; carbonyl compounds;

D O I：

10.1515/znb-2005-0417

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

NaBH4 in the presence of sodium bisulfate (NaHSO(4)center dot H2O), a weakly acidic reagent, efficiently reduces a variety of carbonyl compounds such as aldehydes, ketones, alpha, beta-unsaturated aldehydes and ketones, alpha-diketones and acyloins to their corresponding alcohols in acetonitrile under heterogeneous condition. Reduction reactions were accomplished at room temperature or under reflux condition.

引用

页码：453 / 457

页数：5

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