Radical bulk polymerization of styrene in the presence of fullerene[60]

被引：26
|
作者：
Arsalani, N [1 ]
Geckeler, KE [1 ]
机构：
[1] UNIV TUBINGEN,FAC CHEM & PHARM,INST ORGAN CHEM,D-72076 TUBINGEN,GERMANY
来源：
FULLERENE SCIENCE AND TECHNOLOGY | 1996年 / 4卷 / 05期
关键词：
D O I：
10.1080/10641229608001151
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The polymerization of styrene in the presence of fullerene[60] using AlBN as the initiator as well as under thermal polymerization conditions was investigated. The results indicate that the polymer yields decrease with an increase of the amount of fullerene present during the initiated and thermal polymerization. Thus, an inhibitory effect of fullerene[60] on the radical polymerization of styrene can be concluded. In addition, a mechanism for the free radical polymerization of vinyl monomers in the presence of C-60 is proposed.
引用
收藏
页码：897 / 912
页数：16
相关论文
共 50 条
  • [31] The Micro-environment of Propagating Radical for Styrene in Bulk Polymerization
    毛友钢
    郑莹光
    王国斌
    沈家骢
    ChineseScienceBulletin, 1993, (12) : 1056 - 1056
  • [32] Bulk free radical polymerization of styrene with unsymmetrical bifunctional initiators
    Kim, Kee-Jeong, 1600, (28):
  • [33] On the initial stage of the free-radical polymerizations of styrene and methyl methacrylate in the presence of fullerene C60
    Yumagulova, R. Kh.
    Kuznetsov, S. I.
    Diniakhmetova, D. R.
    Frizen, A. K.
    Kraikin, V. A.
    Kolesov, S. V.
    KINETICS AND CATALYSIS, 2016, 57 (03) : 380 - 387
  • [34] On the initial stage of the free-radical polymerizations of styrene and methyl methacrylate in the presence of fullerene C60
    R. Kh. Yumagulova
    S. I. Kuznetsov
    D. R. Diniakhmetova
    A. K. Frizen
    V. A. Kraikin
    S. V. Kolesov
    Kinetics and Catalysis, 2016, 57 : 380 - 387
  • [35] Bulk polymerization of styrene in presence of polybutadiene: Calculation of molecular macrostructure
    Estenoz, DA
    Valdez, E
    Oliva, H
    Meira, GR
    JOURNAL OF APPLIED POLYMER SCIENCE, 1996, 59 (05) : 861 - 885
  • [36] Bulk polymerization of styrene in presence of polybutadiene: calculation of molecular macrostructure
    INTEC , Santa Fe, Argentina
    J Appl Polym Sci, 5 (861-885):
  • [37] THE BULK POLYMERIZATION OF STYRENE
    VAUGHAN, MF
    JOURNAL OF APPLIED CHEMISTRY, 1952, 2 (07): : 422 - 428
  • [38] Radical bulk polymerization of styrene in the presence of rubber particles from recycled tires: a kinetic study using DSC
    Florez, Daniela
    Hoppe, Sandrine
    Hu, Guo-Hua
    Meimaroglou, Dimitrios
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2021, 143 (04) : 3073 - 3084
  • [39] Radical bulk polymerization of styrene in the presence of rubber particles from recycled tires: a kinetic study using DSC
    Daniela Florez
    Sandrine Hoppe
    Guo-Hua Hu
    Dimitrios Meimaroglou
    Journal of Thermal Analysis and Calorimetry, 2021, 143 : 3073 - 3084
  • [40] Photoinitiated Bulk and Emulsion Polymerization of Styrene - Evidence for Photo-Controlled Radical Polymerization
    Krueger, Kathleen
    Tauer, Klaus
    Yagci, Yusuf
    Moszner, Norbert
    MACROMOLECULES, 2011, 44 (24) : 9539 - 9549
12345