Radical bulk polymerization of styrene in the presence of fullerene[60]

被引：26
|
作者：
Arsalani, N [1 ]
Geckeler, KE [1 ]
机构：
[1] UNIV TUBINGEN,FAC CHEM & PHARM,INST ORGAN CHEM,D-72076 TUBINGEN,GERMANY
来源：
FULLERENE SCIENCE AND TECHNOLOGY | 1996年 / 4卷 / 05期
关键词：
D O I：
10.1080/10641229608001151
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The polymerization of styrene in the presence of fullerene[60] using AlBN as the initiator as well as under thermal polymerization conditions was investigated. The results indicate that the polymer yields decrease with an increase of the amount of fullerene present during the initiated and thermal polymerization. Thus, an inhibitory effect of fullerene[60] on the radical polymerization of styrene can be concluded. In addition, a mechanism for the free radical polymerization of vinyl monomers in the presence of C-60 is proposed.
引用
收藏
页码：897 / 912
页数：16
相关论文
共 50 条
  • [1] The effect of ferrocene on the initial rate of the radical polymerization of styrene in the presence of fullerene C60
    R. Kh. Yumagulova
    N. A. Medvedeva
    S. V. Kolesov
    Polymer Science Series B, 2011, 53
  • [2] The Effect of Ferrocene on the Initial Rate of the Radical Polymerization of Styrene in the Presence of Fullerene C60
    Yumagulova, R. Kh.
    Medvedeva, N. A.
    Kolesov, S. V.
    POLYMER SCIENCE SERIES B, 2011, 53 (7-8) : 371 - 374
  • [3] Radical polymerization of styrene in the presence of C60
    Chen, Y
    Lin, KC
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999, 37 (15) : 2969 - 2975
  • [4] Solvent effect on the kinetics of the free-radical polymerization of styrene in the presence of fullerene C60
    Yumagulova, R. Kh.
    Medvedeva, N. A.
    Kuznetsov, S. I.
    Kraikin, V. A.
    Kolesov, S. V.
    KINETICS AND CATALYSIS, 2014, 55 (01) : 64 - 68
  • [5] Solvent effect on the kinetics of the free-radical polymerization of styrene in the presence of fullerene C60
    R. Kh. Yumagulova
    N. A. Medvedeva
    S. I. Kuznetsov
    V. A. Kraikin
    S. V. Kolesov
    Kinetics and Catalysis, 2014, 55 : 64 - 68
  • [6] Acceleration of vinyl radical polymerization by ferrocene in the presence of fullerene C60
    Puzin, YI
    Yumagulova, RK
    Budtov, VP
    Kolesov, SV
    Monakov, YB
    POLYMER SCIENCE SERIES B, 2005, 47 (3-4) : 72 - 72
  • [7] Radical (co)polymerization of allyl methacrylate in the presence of fullerene C60
    Yumagulova, R. Kh.
    Biglova, Yu. N.
    Kolesov, S. V.
    Monakov, Yu. B.
    DOKLADY CHEMISTRY, 2006, 408 (2) : 90 - 91
  • [8] RADICAL POLYMERIZATION OF STYRENE IN THE PRESENCE OF YLIDE
    SAINI, S
    SHUKLA, AK
    SRIVASTAVA, AK
    POLYMER JOURNAL, 1985, 17 (10) : 1117 - 1121
  • [9] RADICAL POLYMERIZATION OF VINYL MONOMERS IN PRESENCE OF DISULFIDES .1. BULK-POLYMERIZATION OF STYRENE IN PRESENCE OF LINEAR DISULFIDES
    HALLENSLEBEN, ML
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1976, 177 (11): : 3207 - 3212
  • [10] Effect of [60]fullerene on the radical polymerization of alkenes
    Mehrotra, S
    Nigam, A
    Malhotra, R
    CHEMICAL COMMUNICATIONS, 1997, (05) : 463 - 464
12345