Oxidation of Methionine by Tripropylammonium Fluorochromate-A Kinetic and Mechanistic Study

被引：3
|
作者：
Mansoor, S. Sheik [1 ]
机构：
[1] C Abdul Hakeem Coll, Post Grad & Res Dept Chem, Melvisharam 632509, Tamil Nadu, India
来源：
E-JOURNAL OF CHEMISTRY | 2011年 / 8卷 / 02期
关键词：
Tripropylammonium fluorochromate; Methionine; Kinetics; Oxidation; Mechanism; ACETIC-ACID MEDIUM; DL-METHIONINE; CHROMIC-ACID; CHLOROCHROMATE; CHROMIUM(VI); EFFICIENT; ALCOHOLS; REAGENT; OXIDANT;
D O I：
10.1155/2011/945236
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics of oxidation of methionine (Met) by tripropylammonium fluorochromate (TriPAFC) has been studied in the presence of chloroacetic acid in aqueous acetic acid medium. The reaction is first order with respect to methionine, TriPAFC and acid. The reaction rate has been determined at different temperatures and activation parameters calculated. With an increase in the amount of acetic acid in its aqueous mixture, the rate increases. The reaction does not induce polymerization of acrylonitrile. A suitable mechanism has been proposed.
引用
收藏
页码：643 / 648
页数：6
相关论文
共 50 条
  • [31] Kinetics and mechanism of the oxidation of DL-methionine by quinolinium fluorochromate
    Pohani, P
    Sharma, PK
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2004, 81 (09) : 757 - 761
  • [32] Oxidative Regeneration of Carbonyl Compounds from Oximes by Pyridinium Fluorochromate: A Kinetic and Mechanistic Study
    Sharma, Ajay
    Vyas, Neha
    Choudhary, A.
    Prasadrao, P. T. S. R. K.
    Sharma, Vinita
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (05) : 2792 - 2796
  • [33] Effect of excess free energy of solvents on the oxidation of methionine by quinolinium fluorochromate. A kinetic study (vol 73, pg 735, 2008)
    Bhuvaneshwari, D. S.
    Elango, K. P.
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2008, 73 (8-9) : 935 - 935
  • [34] Manganese(III) Oxidation of L-Methionine in Aqueous Acetic Acid Medium: A Kinetic and Mechanistic Study
    Chidankumar, C. S.
    Chandraju, S.
    Gowda, Netkal M. Made
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (10) : 645 - 650
  • [35] Oxidation of 3,4,5-trimethoxybenzaldehyde by pyridinium fluorochromate in N,N-dimethyl formamide medium: A kinetic and mechanistic study
    Hiran, Basanti Lal
    Khuntwal, Jyoti
    Malkani, Raj Kumar
    Singh, Divya
    ARABIAN JOURNAL OF CHEMISTRY, 2016, 9 : S440 - S445
  • [36] Kinetic and mechanistic study of oxidation of l-methionine by Waugh-type enneamolybdomanganate(IV) in perchloric acid
    Gurame, V. M.
    Supale, A. R.
    Gokavi, Gavisiddappa S.
    AMINO ACIDS, 2010, 38 (03) : 789 - 795
  • [37] Kinetic and mechanistic study of oxidation of l-methionine by Waugh-type enneamolybdomanganate(IV) in perchloric acid
    V. M. Gurame
    A. R. Supale
    Gavisiddappa S. Gokavi
    Amino Acids, 2010, 38 : 789 - 795
  • [38] Quinolinium fluorochromate oxidation of benzilic acid in aqueous acetic acid medium: A kinetic study
    Meenakshisundaram, S
    Sathiyendiran, V
    Mahendran, M
    AFINIDAD, 2001, 58 (495) : 341 - 346
  • [39] Kinetic study of methionine oxidation in human parathyroid hormone
    Nabuchi, Y
    Fujiwara, E
    Kuboniwa, H
    Asoh, Y
    Ushio, H
    ANALYTICA CHIMICA ACTA, 1998, 365 (1-3) : 301 - 307
  • [40] A kinetic and mechanistic study on the oxidation of L-methionine and N-acetyl L-methionine by cerium(IV) in sulfuric acid medium
    Sumathi, T.
    Shanmugasundaram, P.
    Chandramohan, G.
    ARABIAN JOURNAL OF CHEMISTRY, 2016, 9 : S177 - S184
12345