Study on 5-(azulen-1-ylmethylene)-2,2-dimethyl-1,3-dioxane-4,6-diones by electrochemical methods

被引：5
|
作者：
Ungureanu, Eleonora-Mihaela [1 ]
Buica, George-Octavian [2 ]
Razus, Alexandru [3 ]
Birzan, Liviu [3 ]
Giol, Elena Diana [1 ]
机构：
[1] Univ Politehn Bucuresti, Fac Appl Chem & Mat Sci, Bucharest 060042, Romania
[2] Petr Gas Univ Ploiesti, Ploiesti 100680, Romania
[3] Romanian Acad, Inst Organ Chem CD Nenitzescu, Bucharest 71141, Romania
来源：
MONATSHEFTE FUR CHEMIE | 2011年 / 142卷 / 03期
关键词：
Azulene-methylene-malonate; Cyclic voltammetry; Differential pulse voltammetry; Computations; AZULENE; BEHAVIOR;
D O I：
10.1007/s00706-011-0445-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electrochemical study of several 5-(azulen-1-ylmethylene)-2,2-dimethyl-1,3-dioxane-4,6-diones was performed by cyclic and differential pulse voltammetry to evaluate the influence of donor and acceptor substituents on their electrochemical behavior. The number and characteristics of the redox processes for each compound were established. The electrochemical parameters have been correlated with ionization potentials and lowest unoccupied molecular orbital energies evaluated through computational methods for the azulene moiety grafted with different functional groups.
引用
收藏
页码：243 / 250
页数：8
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