Preparation of copper oxide modified boron-doped diamond electrodes and its preliminary study for CO2 reduction

被引:0
|
作者
Yetri, N. Y. [1 ]
Ivandini, T. A. [1 ]
Gunlazuardi, J. [1 ]
机构
[1] Univ Indonesia, Dept Chem, Fac Math & Nat Sci, Kampus UI Depok, Depok 16424, Indonesia
关键词
Copper oxide; boron-doped diamond; carbon dioxide; electrochemical reduction;
D O I
10.1088/1757-899X/1/012011
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Preparation of boron-doped diamond (BDD) modified with Cu2O (Cu2O-BDD) electrodes was conducted to study the electrochemical reduction of CO2. The electrodes were prepared by electrochemical reduction using a solution containing 1mM Cu(CH3COO)(2) and 0.1 M CH3COONa (1.1) at pH 5.7 for 60 s. The electrodeposition of Cu2O at BDD surface was performed by chronoamperometry technique at -0.4 V (vs Ag/AgCl). SEM-EDS and XPS were utilized to characterize the electrodes. At Cu2O-BDD electrodes, cyclic voltammetry of dissolved CO2 in 0.1 M NaCl solution exhibited a reduction peak at around -1.3 V (vs Ag/AgCl), indicated the possibility for application in electrochemical reduction of CO2.
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页数:4
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