Effects of Hydroxylamine Sulfate and Sodium Nitrite on Microstructure and Friction Behavior of Zinc Phosphating Coating on High Carbon Steel

被引：3
|
作者：
Xu, Yu-dong [1 ]
Qi, San [1 ]
Wang, Lei [1 ]
Shi, Min [1 ]
Ding, Ning [2 ]
Pang, Zhi-cheng [2 ]
Wang, Quan [1 ]
Peng, Xu-dong [1 ]
机构：
[1] Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Peoples R China
[2] Bengbu Yucheng New Mat Sci & Technol Ltd Co, Bengbu 233000, Peoples R China
来源：
CHINESE JOURNAL OF CHEMICAL PHYSICS | 2015年 / 28卷 / 02期
关键词：
Hydroxylamine sulfate; Accelerator; Phosphate coating; Friction; PERFORMANCE; ALLOY; NI2+;
D O I：
10.1063/1674-0068/28/cjcp1411201
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Hydroxylamine sulfate (HAS) and sodium nitrite are used as the accelerators for zinc phosphate coating on high carbon steel. Phase evolution of phosphate coating was investigated by X-ray diffraction. It is found that the phosphating coatings are mainly composed of hopeite Zn3Fe(PO4)(2)center dot 4H(2)O and phosphophyllite Zn2Fe(PO4)(2)center dot 4H(2)O. The microstructural changes of the phosphate coating, as a function of phosphating time, were evaluated by scanning electron microscopy. Four-ball friction experiments reveal that hydroxylamine sulfate instead of sodium nitrite can effectively reduce the friction coefficient of lubricated phosphating coating. Therefore, it may be expected that HAS will be widely used as a fast and EGO-friendly accelerator in phosphate industry.
引用
收藏
页码：197 / 202
页数：6
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