Modelling and characterization of mixed ionic-electronic conduction in Gd-2(Ti1-xMnx)(2)O-7+y

被引：23
|
作者：
Porat, O
Spears, MA
Heremans, C
Kosacki, I
Tuller, HL
机构：
[1] Crystal Phys. Electroceramics Lab., Dept. of Mat. Sci. and Engineering, Massachusetts Inst. of Technology, Cambridge
来源：
SOLID STATE IONICS | 1996年 / 86-8卷
关键词：
mixed ionic electronic conductivity; nonstoichiometry; defect chemistry; Gd2Ti2O4; pyrochlore; cathode;
D O I：
10.1016/0167-2738(96)00113-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Mixed ionic and electronic conductivity was obtained in Gd2Ti2O7 by doping with Mn. This was confirmed by measuring the nonstoichiometry and the electrical conductivity as a function of oxygen partial pressure, temperature and Mn concentration. The results were combined with the defect and transport models, to derive key thermodynamic and kinetic parameters of Gd2Ti2O7 doped with Mn.
引用
收藏
页码：285 / 288
页数：4
相关论文
共 50 条
  • [41] Synthesis, Characterization, and Transport Properties of New Mixed Ionic-Electronic Conducting V2O5-Polymer Electrolyte Xerogel Nanocomposites
    Department of Chemistry, Northwestern University, Evanston, IL 60208, United States
    不详
    不详
    Chem. Mater., 10 (2418-2420):
  • [42] Synthesis, characterization, and transport properties of new mixed ionic-electronic conducting V2O5-polymer electrolyte xerogel nanocomposites
    Kloster, GM
    Thomas, JA
    Brazis, PW
    Kannewurf, CR
    Shriver, DF
    CHEMISTRY OF MATERIALS, 1996, 8 (10) : 2418 - &
  • [43] IONIC AND ELECTRONIC CONDUCTION OF OXYGEN ION CONDUCTORS IN THE BI2O3-Y2O3 SYSTEM
    WANG, CZ
    XU, XG
    LI, BZ
    SOLID STATE IONICS, 1984, 13 (02) : 135 - 140
  • [44] Effects of structural characteristics on microwave dielectric properties of Li2Mg(Ti1-xMnx)3O8 ceramics
    Zhang, Ping
    Zhao, Yonggui
    JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 647 : 386 - 391
  • [45] Synthesis and ionic conduction of sodium titanate Na2Ti3O7
    I. A. Stenina
    L. D. Kozina
    T. L. Kulova
    A. M. Skundin
    A. A. Chekannikov
    A. B. Yaroslavtsev
    Russian Journal of Inorganic Chemistry, 2016, 61 : 1235 - 1240
  • [46] Synthesis and ionic conduction of sodium titanate Na2Ti3O7
    Stenina, I. A.
    Kozina, L. D.
    Kulova, T. L.
    Skundin, A. M.
    Chekannikov, A. A.
    Yaroslavtsev, A. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2016, 61 (10) : 1235 - 1240
  • [47] Synthesis and characterization of Y2Ti2O7 and ErxY2−xTi2O7 nanofibers
    Kanchan Mondal
    Kaleb Hartman
    Debalina Dasgupta
    George Trifon
    Mallika Dasari
    Journal of Sol-Gel Science and Technology, 2015, 73 : 265 - 269
  • [48] LUMINESCENCE OF EU3+ IN GD-2(ZR1-YTIY)(2)O-7 EU3+
    OTAKI, H
    KIDO, H
    TAKEUCHI, N
    JOURNAL OF MATERIALS SCIENCE LETTERS, 1993, 12 (21) : 1690 - 1692
  • [49] Synthesis and characterization of mixed ionic-electronic conducting Ca0.8Sr0.2Ti0.7Fe0.3O3-α thin film
    Araki, Sadao
    Hoshi, Yasushi
    Hamakawa, Satoshi
    Hikazudani, Susumu
    Mizukami, Fujio
    SOLID STATE IONICS, 2008, 178 (33-34) : 1740 - 1745
  • [50] Characterization of M-O bonds in Y2Ti2O7 and Y2TiO5 with EELS
    Jegadeesan, P.
    Amirthapandian, S.
    Kaur, Gurpreet
    Chandra, Sharat
    Panigrahi, B. K.
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2015, 252 (01): : 206 - 211
12345