A one-dimensional copper(II) coordination polymer containing [Fe(pytpy)2]2+ (pytpy=4′-(4-pyridyl)-2,2′: 6′,2"-terpyridine) as an expanded 4,4′-bipyridine ligand:: a hydrogen-bonded network penetrated by rod-like polymers

被引：44

作者：

Beves, Jonathon E. ^{[1
]}

Constable, Edwin C. ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

Schaffner, Silvia ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

CRYSTENGCOMM | 2008年 / 10卷 / 03期

关键词：

D O I：

10.1039/b713001e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The one-dimensional coordination polymer [{(H2O)(NO3)(2)CuFe(1)(2)}(2)(NO3)(4)center dot 2.15MeCN center dot 5.85H(2)O](n) assembles when the pendant pyridine donors in [Fe(1)(2)](2+) (1 = 4'-(4-pyridyl)2,2': 6',2 ''-terpyridine) are treated with Cu(NO3)(2)center dot 3H(2)O, exemplifying [Fe(1)(2)](2+) as an expanded 4,4'-bipyridine ligand. In the solid state, the polymer chains are threaded through hydrogen-bonded macrocycles comprising coordinated and non-coordinated water molecules and nitrate ions, the macrocycles being motifs within interconnected sheets in the structure.

引用

页码：344 / 348

页数：5

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