Evidence by XAS of tin oxide coating layered double hydroxides

被引:0
|
作者
Intissar, Mourad [1 ]
Briois, Valerie [2 ]
Besse, Jean-Pierre [1 ]
Leroux, Fabrice [1 ]
机构
[1] Univ Clermont Ferrand, CNRS, UMR 6002, Lab Mat Inorgan, F-63177 Aubiere, France
[2] Ctr Univ Paris Sud, LURE, F-91898 Orsay, France
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中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
XAS provides clear evidences that the tetravalent cations are not incorporated within Layered Double Hydroxide (LDH) sheets. The cations are segregated, presenting a local order close to that of SnO2 rutile. However, the nature of the LDH influences slightly the local order probably due to some surface effect microtexture. Variation of the cell parameters for the LDH materials are explained by a substitution of Al cations by divalent cations M(II).
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页码:288 / 290
页数:3
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