Carbonyl transition metal complexes of a silaborate ligand

被引：0

作者：

Wesemann, L ^{[1
]}

Ramjoie, Y ^{[1
]}

Trinkaus, M ^{[1
]}

Spaniol, TP ^{[1
]}

机构：

[1] Tech Hsch Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 1998年 / 09期

关键词：

cluster chemistry; silaborane clusters; carbonyl complexes; silicon coordination; ruthenium complexes;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction between three equivalents of the silaborate [NEt4][MeSiB10H12] (2) and one equivalent of [RU3(CO)(12)] resulted in almost quantitative formation of the mononuclear transition metal complex [NEt4][Ru(CO)(3)(eta(5)-MeSiB10H10)] (5), which was characterized by X-ray structure analysis. The trinuclear ruthenium complex [NEt4][RU3(CO)(8)(eta(5)-MeSiB10H10)] (7) was synthesized in high yield from the reaction of one equivalent of 2 and [Ru-3(CO)(12)]. The cluster 7 reacts with two equivalents of PMe2Ph with substitution of two carbonyl groups to give the substitution product [NEt4][RU3(CO)(6)(PMe2Ph)(2)(eta(5)-MeSiB10H10)] (8).

引用

页码：1263 / 1268

页数：6

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