Co-catalyst and Metal-free CO2 Fixation into Cyclic Carbonates: COPs to the Rescue

被引:2
|
作者
Gascon, Jorge [1 ]
机构
[1] King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr, Adv Catalyt Mat, Thuwal 23955, Saudi Arabia
来源
CHEM | 2019年 / 5卷 / 12期
关键词
CAPTURE; DIOXIDE;
D O I
10.1016/j.chempr.2019.11.010
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The non-redox fixation of CO2 in cyclic and polymeric carbonates is regarded as one of the most promising technologies for small-scale CO2 utilization. Yet, most heterogeneous catalysts reported to date require the use of co-catalysts, harsh reaction conditions, and non-base metals. In this issue of Chem, Yavuz and coworkers report the one-step synthesis of a new covalent organic polymer that circumvents these issues.
引用
收藏
页码:3015 / 3016
页数:2
相关论文
共 50 条
  • [41] Reaction mechanism of metal-free borophene catalyst electrochemical reduction of CO2 2
    Liu, Meiling
    Rao, Fu
    Xu, Tao
    Fu, Qiming
    Liu, Chao
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2024, 701
  • [42] Metal-free Nanoporous Carbon as a Catalyst for Electrochemical Reduction of CO2 to CO and CH4
    Li, Wanlu
    Seredych, Mykola
    Rodriguez-Castellon, Enrique
    Bandosz, Teresa J.
    CHEMSUSCHEM, 2016, 9 (06) : 606 - 616
  • [43] Triazole Appended Metal–Organic Framework for CO2 Fixation as Cyclic Carbonates Under Solvent-Free Ambient Conditions
    Aasif Helal
    Md. Hasan Zahir
    Ahmed Albadrani
    Moayad Mohammed Ekhwan
    Catalysis Letters, 2023, 153 : 2883 - 2891
  • [44] Transition Metal-Free CO2 Fixation into New Carbon-Carbon Bonds
    Cherubini-Celli, Alessio
    Mateos, Javier
    Bonchio, Marcella
    Dell'Amico, Luca
    Companyo, Xavier
    CHEMSUSCHEM, 2018, 11 (18) : 3056 - 3070
  • [45] Synthesis of Methanol and Diols from CO2 via Cyclic Carbonates under Metal-Free, Ambient Pressure, and Solvent-Free Conditions
    Bobbink, Felix D.
    Menoud, Florent
    Dyson, Paul J.
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (09): : 12119 - 12123
  • [46] Strategies for Enhancing the Catalytic Performance of Metal-Organic Frameworks in the Fixation of CO2 into Cyclic Carbonates
    Taherimehr, Masoumeh
    Van de Voorde, Ben
    Wee, Lik H.
    Martens, Johan A.
    De Vos, Dirk E.
    Pescarmona, Paolo P.
    CHEMSUSCHEM, 2017, 10 (06) : 1283 - 1291
  • [47] Robust multivariate metal-porphyrin frameworks for efficient ambient fixation of CO2 to cyclic carbonates
    He, Liang
    Nath, Jayanta Kumar
    Lin, Qipu
    CHEMICAL COMMUNICATIONS, 2019, 55 (03) : 412 - 415
  • [48] B2O3: A heterogeneous metal-free Lewis acid catalyst for carbon dioxide fixation into cyclic carbonates
    Zhao, Li-Yuan
    Chen, Jun-Yue
    Li, Wen-Cui
    Lu, An-Hui
    JOURNAL OF CO2 UTILIZATION, 2019, 29 : 172 - 178
  • [49] Fabrication of a hollow sphere N,S co-doped bifunctional carbon catalyst for sustainable fixation of CO2 to cyclic carbonates
    Ghosh, Anindya
    Reddy, G. Naaresh
    Siddhique, Mohammed P. K.
    Chatterjee, Sauvik
    Bhattacharjee, Sudip
    Maitra, Rahul
    Lyubimov, Sergey E.
    Arzumanyan, Ashot, V
    Naumkin, Alexander
    Bhaumik, Asim
    Chowdhury, Biswajit
    GREEN CHEMISTRY, 2022, 24 (04) : 1673 - 1692
  • [50] A Novel POP-Ni Catalyst Derived from PBTP for Ambient Fixation of CO2 into Cyclic Carbonates
    Wei, Fen
    Qiu, Jiaxiang
    Zeng, Yanbin
    Liu, Zhimeng
    Wang, Xiaoxia
    Xie, Guanqun
    MATERIALS, 2023, 16 (06)