Reaction Between MnO-SiO2-FeO Solid Oxide and Solid Steel Deoxidized by Si and Mn During Heat Treatment at 1473 K (1200 °C)

被引:25
|
作者
Liu, Cheng-song [1 ]
Kim, Kyung-Ho [2 ]
Kim, Sun-Joong [2 ]
Li, Jing-She [1 ]
Ueda, Shigeru [2 ]
Gao, Xu [2 ]
Shibata, Hiroyuki [2 ]
Kitamura, Shin-Ya [2 ]
机构
[1] Univ Sci & Technol Beijing, Sch Met & Ecol Engn, Beijing 100083, Peoples R China
[2] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan
来源
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE | 2015年 / 46卷 / 04期
关键词
INCLUSIONS; ALLOY;
D O I
10.1007/s11663-015-0356-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new method using a confocal scanning laser microscope for melting oxide at 1673 K (1400 degrees C) to produce a diffusion couple, which consists of oxide and an iron-based alloy, has been developed for the investigation of a solid-state reaction between them. It is important to obtain good contact between the Fe-Mn-Si alloy and MnO-SiO2-FeO oxide before the diffusion experiment to observe diffusion of elements between them at 1473 K (1200 degrees C). In this system, the melting point of the oxides is higher than the temperature where the reaction would be observed. The pretreatment involving melting oxide at 1673 K (1400 degrees C) to obtain good contact with the alloy was carried out using a new method. The effect of the pretreatment at 1673 K (1400 degrees C) on the diffusion experiment at 1473 K (1200 degrees C) was minimized by this new method. The effect of diffusion of oxygen on the solid-state reaction between the Fe-Mn-Si alloy and MnO-SiO2-FeO oxide at 1473 K (1200 degrees C) was observed clearly and showed good agreement with Wagner's model of internal oxidation of metal. (C) The Minerals, Metals & Materials Society and ASM International 2015
引用
收藏
页码:1875 / 1884
页数:10
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