Influence of Co doping on crystal structure and electrochemical performances of LiNi0.5Mn1.5O4

被引：10

作者：

Wang, H. ^{[1
]}

Li, J. ^{[1
]}

Yang, S. ^{[1
]}

Zhang, B. ^{[1
]}

Xiao, J. ^{[1
]}

Ren, R. ^{[1
]}

Cui, J. ^{[1
]}

Xiao, W. ^{[2
]}

机构：

[1] Ningxia Univ, Sch Phys Elect Informat Engn, Adv Energy Storage Mat & Devices Lab, Ningxia 750021, Peoples R China

[2] Jiangsu Huafu Storage New Technol Dev Co Ltd, Gaoyou 225600, Peoples R China

来源：

MATERIALS TECHNOLOGY | 2015年 / 30卷 / A2期

基金：

中国国家自然科学基金;

关键词：

LiNi0.5Mn1.5O4; Lithium ion batteries; Cathode material; Doping; Crystal structure; Electrochemical performances; LITHIUM ION BATTERIES; CATHODE MATERIAL; RATE CAPABILITY; COATED LINI0.5MN1.5O4; SPINEL; IMPROVEMENT; PROGRESS; LIMN2O4;

D O I：

10.1179/17535557A15Y.000000008

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

To investigate the influence of Co doping on spinel LiNi0.5Mn1.5O4 cathode, LiNi0.4Co0.1Mn1.5O4 and LiNi0.35Co0.1Mn1.5O4 were designed and successfully synthesised through a polymer assisted method. Inductively coupled plasma, X-ray diffraction, Fourier transform infrared spectra and X-ray photoelectron spectroscopy tests have been carried out. Results show that the compositions of the synthesised samples are consistent with the designed compositions, and Co doping could decrease the degree of cation ordering; Co doping together with octahedral vacancies could induce higher concentration of Mn3+ in the spinel structure. The result of cyclic voltammetry test suggests LiNi0.35Co0.1Mn1.5O4 has the best conductivity, and LiNi0.35Co0.1Mn1.5O4 exhibited the best rate capability among the three spinel cathodes.

引用

页码：A75 / A78

页数：4

共 50 条

[31] Effects of chromium doping on performance of LiNi0.5Mn1.5O4 cathode material
Wang, Wei
Liu, Heng
Wang, Yan
Gao, Chao
Zhang, Jun
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2013, 23 (07) : 2066 - 2070
[32] Effect of Zr doping on LiNi0.5Mn1.5O4 with ordered or disordered structures
Feng, Shaoping
Kong, Xin
Sun, Hongyan
Wang, Baosen
Luo, Tingbi
Liu, Guiyang
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 749 : 1009 - 1018
[33] Influence of Post-annealing in N2 on Structure and Electrochemical Characteristics of LiNi0.5Mn1.5O4
He Shi-ci
Zhang Qian
Liu Wei-wei
Fang Guo-qing
Sato, Yuichi
Zheng Jun-wei
Li De-cheng
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2013, 29 (02) : 329 - 332
[34] Effect of Zr doping on LiNi0.5Mn1.5O4 with ordered or disordered structures
Liu, Guiyang (liuguiyang@tsinghua.org.cn), 2018, Elsevier Ltd (749)
[35] Effects of Al substitution for Ni and Mn on the electrochemical properties of LiNi0.5Mn1.5O4
Zhong, G. B.
Wang, Y. Y.
Zhang, Z. C.
Chen, C. H.
ELECTROCHIMICA ACTA, 2011, 56 (18) : 6554 - 6561
[36] Effects of precursor treatment with reductant or oxidant on the structure and electrochemical properties of LiNi0.5Mn1.5O4
Chang, Zhaorong
Dai, Dongmei
Tang, Hongwei
Yu, Xu
Yuan, Xiao-Zi
Wang, Haijiang
ELECTROCHIMICA ACTA, 2010, 55 (19) : 5506 - 5510
[37] Effect of Hydrothermal Temperature on Structure and Electrochemical Performances of LiNi0.5Mn1.5O4 Cathode Material for Lithium-ion Battery
Wu, Wei
Wang, Li
Liu, Guijuan
Chen, Dan
Wang, Jiangfeng
Liang, Guangchuan
JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS, 2016, 19 (02) : 43 - 49
[38] Intrinsic electrochemical characteristics of one LiNi0.5Mn1.5O4 spinel particle
Nishikawa, Kei
Zettsu, Nobuyuki
Teshima, Katsuya
Kanamura, Kiyoshi
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2017, 799 : 468 - 472
[39] The simulation on thermal stability of LiNi0.5Mn1.5O4/C electrochemical systems
Yang, Kai
Liu, Xuesheng
Lu, Lili
Wang, Songrui
Liu, Pan
JOURNAL OF POWER SOURCES, 2016, 302 : 1 - 6
[40] Effect of annealing treatment on electrochemical property of LiNi0.5Mn1.5O4 spinel
Zhang Bao
Wang Zhi-xing
Guo Hua-jun
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2007, 17 (02) : 287 - 290

← 1 2 3 4 5 →