Structure and magnetic properties in the La1-xEuxBaFeCuO5+δ system

被引：13

作者：

Er-Rakho, L

Nguyen, N ^{[1
]}

Ducouret, A

Samdi, A

Michel, C

机构：

[1] ENSICAEN, CNRS, UMR 6508, Lab CRISMAT, F-14050 Caen, France

[2] Univ Hassan II, EMPM, Fac Sci Ain Chock, Casablanca, Morocco

来源：

SOLID STATE SCIENCES | 2005年 / 7卷 / 02期

关键词：

lanthanides mixed Fe-Cu double perovskite structure; distorted pyramidal iron environments; X-ray diffraction; Fe-57 Mossbauer spectroscopy; magnetic susceptibility; lattice EFG calculations;

D O I：

10.1016/j.solidstatesciences.2004.10.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solid solution La1-xEuxBaFeCuO5+delta synthesized in air with 0 less than or equal to delta less than or equal to 0.13 was studied by X-ray diffraction, Fe-57 Mossbauer spectroscopy and susceptibility measurements. Double perovskite with YBaFeCuO5-type structure was observed except for x = 0 composition which has a cubic cell. Fe and Cu are generally in square pyramidal environments which differ by their distortion: axially compressed for Fe and elongated for Cu. Mossbauer studies showed the existence of pyramidal Fe3+, Fe3+y and octahedral Fe4+. Electric field gradient calculations allowed to better understand the origin of the distortion of the two pyramidal iron sites. (C) 2004 Elsevier SAS. All rights reserved.

引用

页码：165 / 172

页数：8

共 50 条

[41] Crystal structure, magnetic and electronic properties of CoxFe1-xMnP system
Sredniawa, B
Zach, R
Fornal, P
Duraj, R
Bombik, A
Tobola, J
Kaprzyk, S
Niziol, S
Fruchart, D
Bacmann, M
Fruchart, R
Stanek, J
JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 317 : 266 - 273
[42] Structure, ferroelectric properties, and magnetic properties of the La-doped bismuth ferrite
Cheng, Z. X.
Li, A. H.
Wang, X. L.
Dou, S. X.
Ozawa, K.
Kimura, H.
Zhang, S. J.
Shrout, T. R.
JOURNAL OF APPLIED PHYSICS, 2008, 103 (07)
[43] Magnetic properties of La1-xCexCrO3
Winkler, E.
Causa, M. T.
Neumeier, J. J.
Oseroff, S. B.
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 310 (02) : E959 - E961
[44] Magnetic properties of La1-xPrxCrO3
Yoshii, K
Nakamura, A
Ishii, Y
Morii, Y
JOURNAL OF SOLID STATE CHEMISTRY, 2001, 162 (01) : 84 - 89
[45] Crystal structure and magnetic properties of Pr- and Ti-substituted La2RuO5
Riegg, S.
Loidl, A.
Reller, A.
Ebbinghaus, S. G.
MATERIALS RESEARCH BULLETIN, 2013, 48 (11) : 4583 - 4589
[46] STRUCTURE AND MAGNETIC-PROPERTIES OF Y(CO1-XMX)5 COMPOUNDS
CHUANG, YC
WU, CH
CHANG, YC
JOURNAL OF THE LESS-COMMON METALS, 1982, 84 (02): : 201 - 213
[47] STRUCTURE AND MAGNETIC-PROPERTIES OF GD(CO1-XNIX)5 COMPOUNDS
CHUANG, YC
WU, CH
LI, TC
CHANG, SC
WANG, MS
JOURNAL OF THE LESS-COMMON METALS, 1981, 78 (02): : 219 - 226
[48] Structure and electronic properties of La(Ni,Al)5 alloys
Smardz, L
Smardz, K
Nowak, M
Jurczyk, M
CRYSTAL RESEARCH AND TECHNOLOGY, 2001, 36 (12) : 1385 - 1392
[49] Electrical and magnetic properties of La deficient superconductor La1-xOFeP
Jin, Xinzhe
Watanabe, Tadataka
Takase, Kouichi
Takano, Yoshiki
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 488 (01) : L14 - L16
[50] CRYSTAL-STRUCTURE, ELECTRICAL AND MAGNETIC-PROPERTIES OF LA1-XSRXCOO3-Y
PETROV, AN
KONONCHUK, OF
ANDREEV, AV
CHEREPANOV, VA
KOFSTAD, P
SOLID STATE IONICS, 1995, 80 (3-4) : 189 - 199

← 1 2 3 4 5 →