SO42-/ZrO2:: An efficient catalyst for nitration of chlorobenzene to chloronitrobenzene.

被引:0
|
作者
Parida, KM [1 ]
Pattnayak, PK [1 ]
机构
[1] Reg Res Lab, Bhubaneswar 751013, Orissa, India
关键词
sulphated zirconia; nitration; chlorobenzene;
D O I
暂无
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The nitration of Chlorobenzene was carried out in presence of sulphated zirconia as catalyst at room temperature - 70 degrees C in CCl4 medium using stoichiometric quantity of nitric acid and acetic anhydride. The isolated yield was found to be more than 95% with 90% selectivity to para-isomer. The catalyst can be recycled at least for 5 times with a little decrease in its activity.
引用
收藏
页码:247 / 250
页数:4
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