Halogenation of aromatic methyl ketones using Oxone® and sodium halide

被引：35
|
作者：
Kim, EH
Koo, BS
Song, CE
Lee, KJ [1 ]
机构：
[1] Hanyang Univ, Dept Ind Chem, Seoul 133791, South Korea
[2] Korea Inst Sci & Technol, Seoul 136791, South Korea
来源：
SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 23期
关键词：
D O I：
10.1081/SCC-100107011
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aromatic methyl ketones undergo alpha -halogenation on treatment with sodium halide in the presence of oxone (R) in aqueous methanol. However, electron-rich hetero aromatic methyl ketones afford ring bromination products preferentially.
引用
收藏
页码：3627 / 3632
页数：6
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