Preparation of monoglycerides by guanidine-catalyzed processes

被引：10
|
作者：
Aguiar, LMG [1 ]
Vargas, RM [1 ]
机构：
[1] Univ Fed Bahia, Inst Chem, BR-40170280 Salvador, BA, Brazil
来源：
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1998年 / 75卷 / 06期
关键词：
glycerolysis; guanidines; methyl stearate; monoglycerides;
D O I：
10.1007/s11746-998-0221-6
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Glycerolysis of methyl stearate and tristearin has been carried out in the presence of alkylguanidines-strong nonionic bases-as catalysts. When applied at 10 mol%, 1,5,7-triazabicyclo[4.4.0]dec-5-ene, 1,2,3-tricyclohexylguanidine, and 1,3-dicyclohexyl-2-n-octylguanidine give monoglycerides in more than 90% selectivity, in a maximum of 6 h reaction time.
引用
收藏
页码：755 / 756
页数：2
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