Halogenation of N-substituted p-quinone monoimines and p-quinone monooxime esters:: VII.: Halogenation of 4-aroyl(arylsulfonyl)imino- and 4-aroyl(arylsulfonyl)oxyimino-2,6-diisopropylcyclohexa-2,5-dien-1-ones

被引：6

作者：

Avdeenko, A. P. ^{[1
]}

Pirozhenko, V. V. ^{[2
]}

Shishkin, O. V. ^{[3
]}

Shishkina, S. V. ^{[3
]}

Konovalova, S. A. ^{[1
]}

Ludchenko, O. N. ^{[1
]}

机构：

[1] Donbass State Machine Bldg Acad, UA-84313 Kramatorsk, Ukraine

[2] Natl Acad Sci Ukraine, Inst Organ Chem, Kiev, Ukraine

[3] Natl Acad Sci Ukraine, Inst Single Crystals, Kharkov, Ukraine

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 44卷 / 04期

关键词：

D O I：

10.1134/S1070428008040131

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Halogenation of 4-aroyl(arylsulfonyl)imino-2,6-diisopropylcyclohexa-2,5-dien-1-ones gave 4-aroyl(arylsulfonyl)imino-3-halo-2,6-diisopropylcyclohexa-2,5-dien- -1-ones and 4-aroyl(arylsulfonyl)imino-3,5,6-trihalo-2,6-diisopropylcyclobex-2-en-1-ones. The latter were formed as mixtures of two stereoisomers, and the isopropyl group on the sp(3)-hybridized carbon atom in one stereoisomer occupies axial position, which is untypical of such compounds. Halogenation of 4-aroyl(arylsulfonyl)oxyimino-2,6-diisopropylcyclohexa-2,5-dien-1-ones leads to the formation of the corresponding addition products with traditional trans-diaxial arrangement of the halogen atoms.

引用

页码：542 / 552

页数：11

共 24 条

[21] Halogenation of N-substituted p-quinone monoimines and p-quinonemonooxime ethers: XII. Halogenation of N-aroyl-2(3)-methyl-1,4-benzoquinone monoimines and their reduced forms
A. P. Avdeenko
S. A. Konovalova
O. N. Ludchenko
Russian Journal of Organic Chemistry, 2010, 46 : 1629 - 1638
[22] Halogenation of N-substituted p-Quinone Monoimines and p-Quinonemonooxime Ethers: XII. Halogenation of N-Aroyl-2(3)-methyl-1,4-benzoquinone Monoimines and Their Reduced Forms
Avdeenko, A. P.
Konovalova, S. A.
Ludchenko, O. N.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 46 (11) : 1629 - 1638
[23] Halogenation of N-substituted p-quinonimines and p-quinone oxime esters: I. Chlorination and bromination of 4-aroyloxyimino- and arylsulfonyloxyimino-2,5-cyclohexadienones
Avdeenko A.P.
Shishkina S.V.
Shishkin O.V.
Glinyanaya N.M.
Konovalova S.A.
Goncharova S.A.
Russian Journal of Organic Chemistry, 2002, 38 (5) : 683 - 691
[24] Halogenation of N-substituted p-quinonimines and p-quinone oxime esters:: I.: Chlorination and bromination of 4-aroyloxyimino- and arylsulfonyloxyimino-2,5-cyclohexadienones
Shishkina, SV
Shishkina, SV
Shishkin, OV
Glinyanaya, NM
Konovalova, SA
Goncharova, SA
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 38 (05) : 683 - 691

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