Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(II) catalysts

被引：58
|
作者：
Colladon, Marco [1 ]
Scarso, Alessandro [1 ]
Strukul, Giorgio [1 ]
机构：
[1] Univ Ca Foscari Venezia, Dipartimento Chim, I-30123 Venice, Italy
来源：
GREEN CHEMISTRY | 2008年 / 10卷 / 07期
关键词：
D O I：
10.1039/b805404e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bridging hydroxo complexes of Pt(II) can be used as catalysts for the oxidation of tertiary and secondary amines under mild conditions using the environmentally benign hydrogen peroxide as the oxidant. The reaction proceeds with medium to excellent yields particularly in the case of the more electron rich tertiary amines.
引用
收藏
页码：793 / 798
页数：6
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