Effect of Molecular Weight on Phase Diagram of Epoxy/Polyetherimide-Siloxane Blends

被引：0
|
作者：
Li, Xiaoyan [1 ]
Gan, Wenjun [2 ]
Ren, Yuan [1 ]
Xi, Zheng [1 ]
Tang, Yanwen [2 ]
Gu, Shengjie [2 ]
机构：
[1] Shanghai Univ Engn Sci, Coll Mat Engn, Shanghai 201620, Peoples R China
[2] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China
来源：
MANUFACTURING PROCESS TECHNOLOGY, PTS 1-5 | 2011年 / 189-193卷
关键词：
Epoxy; Polyetherimide-Siloxane; Phase Diagram; Reaction Induced Phase Separation; SEPARATION PROCESS; BEHAVIOR;
D O I：
10.4028/www.scientific.net/AMR.189-193.1127
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The cloud points of blends epoxy/polyetherimide-siloxane (PEI-Siloxane) without or with curing agent methyl tetrahydrophthalic anhydride (Me-THPA) after different curing time (1 min, 2min, 3min) at 150 degrees C were determined by optical microscope. The cloud point curve for uncured and cured after different time was then obtained from the experimental results with different composition. The effects of molecular weight of epoxy on phase diagram were discussed. The miscibility of blends will be taken into account in the toughing of epoxy resins by thermoplastic PEI-Siloxane copolymer later.
引用
收藏
页码：1127 / +
页数：2
相关论文
共 50 条
  • [31] MOLECULAR-WEIGHT EFFECT UPON PHASE-DIAGRAM OF PEO-NASCN MIXTURES
    BOILSBOISSIER, D
    PRUDHOMME, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 174 - PMSE
  • [32] EFFECT OF MOLECULAR-WEIGHT ON THE PHASE-DIAGRAM OF POLYETHYLENE UNDER HIGH-PRESSURE
    YASUNIWA, M
    HARAGUCHI, K
    NAKAFUKU, C
    HIRAKAWA, S
    POLYMER JOURNAL, 1985, 17 (11) : 1209 - 1219
  • [33] EFFECT OF MOLECULAR-WEIGHT ON THE PHASE-DIAGRAM OF LINEAR POLYETHYLENE IN 1-DODECANOL
    CHIU, G
    MANDELKERN, L
    MACROMOLECULES, 1990, 23 (26) : 5356 - 5357
  • [34] Effect of cure accelerator on phase morphology in epoxy/polysulfone blends
    Tsinghua Univ, Beijing, China
    Cailiao Yanjiu Xuebao/Chinese Journal of Materials Research, 1998, 12 (06): : 615 - 618
  • [35] Determination of the phase boundary of high molecular weight polymer blends
    Lefebvre, AA
    Balsara, NP
    Lee, JH
    Vaidyanathan, C
    MACROMOLECULES, 2002, 35 (20) : 7758 - 7764
  • [36] Effect of hydroxyl-terminated polyethersulfone on the phase separation of polyetherimide-modified epoxy resin
    Zhang, ZC
    Cui, J
    Li, SJ
    Sun, K
    Fan, WZ
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2001, 202 (01) : 126 - 132
  • [37] Miscibility phase diagram of ring-polymer blends: A topological effect
    Sakaue, Takahiro
    Nakajima, Chihiro H.
    PHYSICAL REVIEW E, 2016, 93 (04)
  • [38] The Effect of Molecular Weight of Glycols on the Properties of Epoxy Resins
    Ladaniuc, Magdalena Adriana
    Dumitrache, Liviu
    Raditoiu, Alina
    Paven, Horia
    Gabor, Raluca
    Hubca, Gheorghe
    MATERIALE PLASTICE, 2012, 49 (02) : 95 - 98
  • [39] Effect of Pressure on the Phase Behavior and Segmental Dynamics in Blends of Polystyrene with Poly(methylphenyl siloxane)
    Gitsas, Antonis
    Floudas, George
    White, Ronald P.
    Lipson, Jane E. G.
    MACROMOLECULES, 2009, 42 (15) : 5709 - 5716
  • [40] Phase behavior of binary blends of high molecular weight diblock copolymers with a low molecular weight triblock
    Mickiewicz, Rafal A.
    Ntoukas, Eleftherios
    Avgeropoulos, Apostolos
    Thomas, Edwin L.
    MACROMOLECULES, 2008, 41 (15) : 5785 - 5792
12345