On the hydrolysis of 2,3-dihydro-1,3-di-tert-butyl-4,5-dimethylimidazol-2-ylidene.: The crystal structure of 1,3-di-tert-butyl-4,5-dimethylimidazolium bicarbonate [1]

被引：10

作者：

Abu-Rayyan, Ahmed

Abu-Salem, Qutaiba ^{[1
]}

Kuhn, Norbert ^{[1
]}

Maichle-Moessmer, Caecilia ^{[1
]}

Steimann, Manfred ^{[1
]}

Henkel, Gerald ^{[2
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

[2] Fachbereich Chem Univ, Paderborn, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 05期

关键词：

carbenes; carbonates; hydrogen bonds; crystal structures;

D O I：

10.1002/zaac.200700576

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,3-Di-tert-butyl-4,5-dimethylimidazolium bicarbonate (7), formed on the exposure of 2,3-dihydro-1,3-di-tert-butyl-4,5-dimethylimidazol-2-ylidene (6) towards air, is prepared on the reaction of 6 with ammonium bicarbonate; its crystal structure analysis reveals the presence of dimeric bicarbonate anions linked to each other and to the imidazolium ions with hydrogen bonds.

引用

页码：823 / 824

页数：2

共 50 条

[31] The surprising reactions of 1,3-di-tert-butyl-2,2-dichloro-1,3-diaza-2-germa-4-cyclopentene
West, Robert
Moser, Daniel F.
Guzei, Ilia A.
Lee, Gyu-Hwan
Naka, Akinobu
Li, Wenjian
Zabula, Alexander
Bukalov, Sergei
Leites, Larissa
ORGANOMETALLICS, 2006, 25 (11) : 2709 - 2711
[32] CRYSTAL AND MOLECULAR STRUCTURE OF HETEROAROMATICS WITH TERT BUTYL GROUPS AT ORTHO POSITIONS .1. 2,3-DI TERT BUTYLQUINOXALINE AT -160 DEGREES C
VISSER, GJ
VOS, A
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (SEP15): : 1793 - &
[33] Synthesis and crystal structure of 1,3-di-tert-butyl-2-chloro-4,4-diphenyl-1,3,2λ3,4-diazaphosphasiletudine
Mo, Dennis
Frank, Walter
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 405 - +
[34] Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo4,5- dihydro-1H-pyrrole-3-carboxylate
Rosen, Gerald M.
Muralidharan, Sukumaran
Zavalij, Peter Y.
Fletcher, Steven
Kao, Joseph P. Y.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O878 - +
[35] THE DYNAMIC STEREOCHEMISTRY OF SOME DICARBONYL[PHOSPHORUS(III)](1,3-DI-TERT-BUTYL-2-METHOXYARENE)CHROMIUM COMPOUNDS - EVIDENCE FOR RESTRICTED ROTATION ABOUT ARENE SUBSTITUENT BONDS, INCLUDING AN X-RAY CRYSTAL-STRUCTURE OF DICARBONYL(TRIPHENYLPHOSPHINE)(1,3-DI-TERT-BUTYL-2-METHOXYBENZENE)CHROMIUM
CAMPI, EM
GATEHOUSE, BMK
JACKSON, WR
RAE, ID
WONG, MG
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (03) : 175 - 176
[36] 1,3-di(tert-butyl)-2,4-di(tert-butylamido)-2,4-dimethylcyclodisilazane: A chelating ancillary diamide ligand for transition metals
Grocholl, L
Stahl, L
Staples, RJ
INORGANIC CHEMISTRY, 1998, 37 (19) : 5036 - 5038
[37] Synthesis and molecular structure of (1,3-dimethyl-4,5-dimethylimidazol-2-ylidene)ag(I)(benzoate)
Chung, M
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2002, 23 (08) : 1160 - 1162
[38] Di-tert-butyl 2,6,11-trioxo-2,3-dihydro-1H-anthra[1,2-d]imidazole-1,3-diacetate
Afrakssou, Zahra
Rodi, Yousef Kandri
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1730 - U1065
[39] REARRANGEMENTS OF 2,6-DI-TERT-BUTYL-4-(1,3-DIOXACYCLO-2-ALKYL)PHENOXYL RADICALS IN SOLUTION
SKURKO, MR
KUKOVITSKII, DM
ZLOTSKII, SS
BELOV, PS
RAKHMANKULOV, DL
ZHURNAL ORGANICHESKOI KHIMII, 1980, 16 (06): : 1340 - 1341
[40] Highly substituted dienes and polyenes, IX - The molecular structure of 4-tert-butyl-5,5-dimethyl-1,3-hexadiene(1,1-di-tert-butyl-1,3-butadiene)
Hopf, H
Hanel, R
Traetteberg, M
Bakken, P
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 1998, 1998 (03) : 467 - 472

← 1 2 3 4 5 →