Dichloridobis[N-(2-pyridylmethyl)-benzamide-κ2N,O]cadmium(II)

被引：1
|
作者：
Zhang, Shu-Fang [1 ]
Yang, Xiao-Gang
Liu, Zhi
Xu, Feng-Ling
Hou, Bao-Rong
机构：
[1] Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807031054
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [CdCl2(C13H12N2O)(2)], the Cd-II ion is situated on an inversion centre, coordinated by two 0 atoms [Cd-O=2.3878 (17) angstrom] and two N atoms [Cd-N = 2.3404 (15) angstrom] from two N-(2-pyridylmethyl)benzamide ligands, and two Cl atoms [Cd-Cl = 2.5566 (6) angstrom], in a distorted octahedral geometry. In the crystal structure, intermolecular N-H center dot center dot center dot Cl hydrogen bonds [N center dot center dot center dot Cl = 3.1705 (18) angstrom] and pi-pi interactions, with a distance of 3.868 (3) angstrom between the centroids of the phenyl and pyridyl rings of neighbouring molecules, lead to the formation of two-dimensional layers parallel to the bc plane.
引用
收藏
页码：M2058 / U330
页数：11
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