AIE-active tetraphenylethene functionalized metal-organic framework for selective detection of nitroaromatic explosives and organic photocatalysis

被引：150
|
作者：
Li, Qiu-Yan [1 ]
Ma, Zheng [1 ]
Zhang, Wen-Qiang [1 ]
Xu, Jia-Long [1 ]
Wei, Wei [1 ]
Lu, Han [1 ]
Zhao, Xinsheng [2 ]
Wang, Xiao-Jun [1 ]
机构：
[1] Jiangsu Normal Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Peoples R China
[2] Jiangsu Normal Univ, Sch Phys & Elect Engn, Xuzhou 221116, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 75期
关键词：
AGGREGATION-INDUCED EMISSION; DEHYDROGENATIVE-COUPLING REACTION; VISIBLE-LIGHT; 2,4,6-TRINITROPHENOL TNP; COORDINATION POLYMERS; HIGHLY EFFICIENT; ENERGY-TRANSFER; LUMINESCENCE; FLUORESCENCE; CATALYSIS;
D O I：
10.1039/c6cc04997d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
AIE-active luminogen tetraphenylethene (TPE) was incorporated into a UiO-isoreticular zirconium metal-organic framework via the strategy of mixed dicarboxylate struts, and the resulting functionalized MOF shows a strong blue-green emission and selective sensing of nitroaromatic explosives 2,4,6-trinitrophenol (TNP) and 2,4-dinitrophenol (DNP) through fluorescence quenching. Moreover, the luminescent MOF exhibits efficient photocatalytic activity for aerobic cross-dehydrogenative coupling reactions mediated by visible light.
引用
收藏
页码：11284 / 11287
页数：4
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