Triphenylarsine as an Efficient Catalyst in Diastereospecific Synthesis of N-Vinyl Heterocyclic Compounds

被引：9

作者：

Maghsoodlou, Malek Taher ^{[1
]}

Heydari, Reza ^{[1
]}

Habibi-Khorassani, Sayyed Mostafa ^{[1
]}

Hazeri, Nourollah ^{[1
]}

Lashkari, Mojtaba ^{[1
]}

Rostamizadeh, Mohsen ^{[1
]}

Sajadikhah, Seyed Sajad ^{[1
]}

机构：

[1] Univ Sistan & Baluchestan, Dept Chem, Zahedan, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2011年 / 41卷 / 04期

关键词：

Dialkyl acetylenedicarboxylate; N-H heterocyclic compounds; N-vinylation; triphenylarsine; STABLE PHOSPHORUS YLIDES; DIELS-ALDER REACTION; ONE-POT SYNTHESIS; ACETYLENIC ESTERS; ANTIPARASITIC NITROIMIDAZOLES; AMINE-DERIVATIVES; NITROGEN; TRIPHENYLPHOSPHINE; ENAMIDES; 1-VINYLIMIDAZOLE;

D O I：

10.1080/00397911003629432

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[image omitted] A diastereospecific synthesis of N-vinyl heterocyclic compounds is described from a reaction of dialkyl acetylenedicarboxylate and N-H heterocyclic compounds, such as phthalimide, saccharin, 3(2H)-pyridazinone, isatin, maleimide, 2,4-thiazolidinedione, 2-benzoxazolinione and 6-chloro-2-benzoxazolinione, in the presence of triphenylarsine as an efficient catalyst, in excellent yield. The presented one-pot method is simple and effective with mild conditions.

引用

页码：569 / 578

页数：10

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