Ruthenium-catalyzed asymmetric hydrosilylation of ketones and imine

被引：169
|
作者：
Nishibayashi, Y
Takei, I
Uemura, S [1 ]
Hidai, M
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan
[2] Univ Tokyo, Dept Chem & Biotechnol, Grad Sch Engn, Tokyo 1138656, Japan
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 16期
关键词：
D O I：
10.1021/om980399o
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ruthenium complexes with (oxazolinylferrocenyl)phosphines, RuCl2(PPh3)((oxazolinylferrocenyl)-phosphine), have been prepared and characterized by spectroscopy. these ruthenium complexes are very effective catalysts for asymmetric hydrosilylation of not only ketones but also an imine to give the corresponding sec-alcohols (up to 97% ee) and a sec-amine (88% ee) after acid hydrolysis, respectively.
引用
收藏
页码：3420 / 3422
页数：3
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