Electrochemical synthesis of spiroisoxazole derivatives and its application to natural products

被引：0
|
作者：
Ogamino, T [1 ]
Ishikawa, Y [1 ]
Nishiyama, S [1 ]
机构：
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
来源：
HETEROCYCLES | 2003年 / 61卷
关键词：
spiroisoxazole; anodic oxidation; zamamistatin; dibromophenylpyruvic acid oxime; phenolic oxidation;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Efficient synthesis of the trans-spiroisoxazole (1) and its unnatural cis-isomer (2) was accomplished by employing anodic oxidation of 4, followed by Zn(BH4)(2) reduction. This method was applied to an assembly of the carbon framework of zamamistatin (12).
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页码：73 / +
页数：7
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