Porous, covalent triazine-based frameworks prepared by ionothermal synthesis

被引：2186

作者：

Kuhn, Pierre ^{[1
]}

Antonietti, Markus ^{[1
]}

Thomas, Arne ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 18期

关键词：

crystalline organic networks; ionothermal polymerization; porous polymers; triazine; trimerizations;

D O I：

10.1002/anie.200705710

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Ordered and amorphous microporous polytriazine networks have been obtained from the trimerization of nitriles in a ZnCl2 melt at 400°C (see structure of the polymer formed from 1,4-dicyanobenzene; C gray, N blue). The materials are high-performance polymers with very large surface areas and could find applications in gas storage, as sensors, or catalyst supports. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3450 / 3453

页数：4

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