Synthesis of carbonates directly from 1 atm CO2 and alcohols using CH2Cl2

被引：26
|
作者：
Yamazaki, Yusuke [1 ]
Kakuma, Kasumi [1 ]
Du, Ya [1 ]
Saito, Susumu [1 ,2 ]
机构：
[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Inst Adv Res, Chikusa Ku, Nagoya, Aichi 4648601, Japan
来源：
TETRAHEDRON | 2010年 / 66卷 / 51期
关键词：
1 atm Carbon dioxide; Dichloromethane; Carbonate; Alcohol; Cesium carbonate; PRIMARY ALIPHATIC-AMINES; DIMETHYL CARBONATE; CATALYZED SYNTHESIS; CARBOXYLIC-ACIDS; PROPYLENE CARBONATE; NAY FAUJASITE; DIOXIDE; ALLYL; HYDROGENATION; PALLADIUM;
D O I：
10.1016/j.tet.2010.10.051
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We introduced here a new one-pot, general procedure for the preparation of dialkyl carbonates from alcohols in a straightforward fashion under 1 atm pressure of CO2 using Cs2CO3 and CH2Cl2 as key reagents. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：9675 / 9680
页数：6
相关论文
共 50 条
  • [41] STRUCTURE OF [CH3S(CH2)2SCH3MO(CO)3(SNCL3)CL](CH2CL2)
    ANDERSON, RA
    EINSTEIN, FWB
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (MAR15): : 966 - 968
  • [42] (Perylene)Co(mnt)2(CH2Cl2)0.5. A mixed molecular and polymeric conductor
    1986, (114):
  • [43] *TENSIONS DE VAPEUR DU SYSTEME CH3CL - CH2CL2
    GANEFF, JM
    JUNGERS, JC
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1948, 57 (1-4): : 82 - 87
  • [44] Synthesis of dialkyl carbonates from CO2 and alcohols via electrogenerated N-heterocyclic carbenes
    Wu, La-Xia
    Wang, Huan
    Xiao, Yan
    Tu, Zhuo-Ying
    Ding, Bin-Bin
    Lu, Jia-Xing
    ELECTROCHEMISTRY COMMUNICATIONS, 2012, 25 : 116 - 118
  • [45] A new method for the regio and stereoselective hydrocarboxylation of alkynes using NaHFe(CO)(4)/CH2Cl2 system
    Periasamy, M
    Radhakrishnan, U
    Rameshkumar, C
    Brunet, JJ
    TETRAHEDRON LETTERS, 1997, 38 (09) : 1623 - 1626
  • [46] Organocatalyzed Synthesis of Oleochemical Carbonates from CO2 and Renewables
    Buettner, Hendrik
    Steinbauer, Johannes
    Wulf, Christoph
    Dindaroglu, Mehmet
    Schmalz, Hans-Guenther
    Werner, Thomas
    CHEMSUSCHEM, 2017, 10 (06) : 1076 - 1079
  • [47] Template Based Electrochemical Synthesis of Copper (Cu) Nanowires as CH2Cl2 Sensor
    Gupta, Jyoti
    Arya, Sandeep
    Singh, Anoop
    Verma, Sonali
    Sharma, Asha
    Singh, Bikram
    Tomar, Amit
    INTEGRATED FERROELECTRICS, 2020, 204 (01) : 63 - 72
  • [48] Picosecond IR study of UV-induced peroxide decomposition:: Formation and vibrational relaxation of CO2 in CH2Cl2 solution
    Buback, M
    Kling, M
    Seidel, MT
    Schott, FD
    Schroeder, J
    Steegmüller, U
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2001, 215 : 717 - 735
  • [49] Dissociative electron attachment to CH2Cl2, CHCH3Cl2, and C(CH3)2Cl2
    Gallup, Gordon A.
    Fabrikant, Ilya I.
    JOURNAL OF CHEMICAL PHYSICS, 2011, 135 (13):
  • [50] Synthesis of azetidinylidene complexes from [(CO)5M(CH2Cl2)], phenylacetylene and imines and oxidative decomplexation to give β-lactams
    Abd-Elzaher, MM
    Fischer, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 588 (02) : 235 - 241
12345