Neutron diffraction study of the atomic structure of the ferroelectric phase of (CH3)2NH2Al(SO4)2.6H2O ferroelectric-ferroelastic (DMAAS)

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作者
Kazimirov, VY [1 ]
Sarin, VA
Ritter, C
Shuvalov, LA
机构
[1] Russian Acad Sci, Inst Nucl Res, Moscow, Russia
[2] Joint Nucl Res Inst, Dubna, Moscow Oblast, Russia
[3] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
[4] Russian Acad Sci, AV Shubnikov Crystallog Inst, Moscow 117333, Russia
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中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The ferroelastic phase of a DMAAS single crystal is studied by the neutron diffraction method on a four-circle automatic diffractometer (lambda = 0.8457 Angstrom) at the Laue-Langevin Institute, Grenoble, France. The crystal structure of the ferroelastic phase is refined up to R = 2.54%, It is established that the ferroelastic phase is characterized by the partial disorder of dimethyl ammonium cation over the positions of amine and methyl groups.
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页码:56 / 61
页数:6
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