High-pressure alkylation of azomethines 1.: Synthesis of N-monoalkylanilines

被引：2

作者：

Agafonov, NE ^{[1
]}

Dudin, AV ^{[1
]}

Preobrazhenskii, AA ^{[1
]}

Zhulin, VM ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 05期

关键词：

azomethines; alkylation; immonium salts; N-monoalkylanilines; high pressure;

D O I：

10.1007/BF02494657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of anils with alkyl halides under high pressure (10 kbar) was studied. Alkylation in polar media (dioxane or acetonitrile) followed by hydrolysis yields pure N-monoalkylanilines in high yields. Optimum conditions for high-pressure alkylation were found.

引用

页码：1005 / 1007

页数：3

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