Aerobic oxidation of amines to imines catalyzed by bulk gold powder and by alumina-supported gold

被引：200

作者：

Zhu, Bolin ^{[1
,2
]}

Lazar, Mihaela ^{[3
]}

Trewyn, Brian G. ^{[1
,2
]}

Angelici, Robert J. ^{[1
,2
]}

机构：

[1] Iowa State Univ, Ames Lab, Ames, IA 50011 USA

[2] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

[3] Natl Inst Res & Dev Isotop & Mol Technol, Cluj Napoca 400293, Romania

来源：

JOURNAL OF CATALYSIS | 2008年 / 260卷 / 01期

关键词：

Amine; Gold; Heterogeneous catalysis; Imine; Oxidation; Oxygen;

D O I：

10.1016/j.jcat.2008.08.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Both bulk gold powder (similar to 50 mu m particle size) and alumina-supported gold (50-150 nm) are highly active catalysts for the aerobic oxidative dehydrogenation of amines (CH-NH) to imines (C=N) under the mild conditions of 1 atm O-2 and 100 degrees C. Reactions using the 5% Au/Al2O3 catalyst make efficient use of the gold metal and offer a practical synthesis of imines from amines. These studies add to the growing list of reactions that are catalyzed by bulk gold metal. (C) 2008 Elsevier Inc. All rights reserved.

引用

页码：1 / 6

页数：6

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