Synthesis of naphtho[b]cyclobutenes from 1,2-bis(3-propynol)benzenes

被引：15

作者：

Kitagaki, S ^{[1
]}

Okumura, Y ^{[1
]}

Mukai, C ^{[1
]}

机构：

[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Div Pharmaceut Sci, Kanazawa, Ishikawa 9201192, Japan

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 11期

关键词：

bisallenes; 2+2] cycloaddition; naphtho[b]cyclobutenes; dephosphinylation;

D O I：

10.1016/j.tetlet.2005.12.121

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have demonstrated that the reaction of benzene-bridged bis(propargyl alcohol)s with chlorodialkylphosphines exclusively afforded 3,8-bis(dialkylphosphinyl)naphtho[b]cyclobutenes via the [2+2] cycloaddition of 1,2-bis(alpha-phosphinylallenyl)benzenes. Dephosphinylation of the product has also been achieved. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1849 / 1852

页数：4

共 50 条

[21] THE SYNTHESIS OF 1,2-BIS(PHENYLSULFONYL)CYCLOALKENES
HERBERT, KA
BANWELL, MG
SYNTHETIC COMMUNICATIONS, 1989, 19 (1-2) : 327 - 337
[22] Stereoselective synthesis of 1,2-bis(boronates)
Ji, Chong-Lei
Gao, De -Wei
TRENDS IN CHEMISTRY, 2024, 6 (04): : 211 - 212
[23] ARSINOCARBORANES . SYNTHESIS AND CHARACTERIZATION OF 1,2-BIS(DIMETHYLARSINO)- AND 1,2-BIS(DIPHENYLARSINO)-O-CARBORANES
SMITH, HD
INORGANIC CHEMISTRY, 1969, 8 (03) : 676 - &
[24] 1,2-BIS(3-PROPARGYLOXYPHENOXY)ETHANE - SYNTHESIS AND POLYMERIZATION
LUCOTTE, G
DELFORT, B
POLYMER BULLETIN, 1991, 26 (01) : 1 - 6
[25] 1,2-Bis(benzyloxy)-1,2-bis(4-chlorophenyl)-3,8-dimethoxyacenaphthene
Takada, Teruhisa
Hijikata, Daichi
Okamoto, Akiko
Oike, Hideaki
Yonezawa, Noriyuki
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2562 - U1735
[26] Crystal chemistry of protonated 1,2-bis(di-R-aminomethyl)benzenes. Part I: 1,2-bis(dimethylaminomethyl)benzene perchlorate
Bartoszak-Adamska, E.
Jaskolski, M.
Brzezinski, B.
Journal of Molecular Structure, 446 (03):
[27] Crystal chemistry of protonated 1,2-bis(di-R-aminomethyl)benzenes. Part I: 1,2-bis(dimethylaminomethyl)benzene perchlorate
Bartoszak-Adamska, E
Jaskolski, M
Brzezinski, B
JOURNAL OF MOLECULAR STRUCTURE, 1998, 446 (03) : 229 - 234
[28] Crystal chemistry of protonated 1,2-bis(di-R-aminomethyl)benzenes -: Part III.: 1,2-bis(diethylaminomethyl)benzene perchlorate
Bartoszak-Adamska, E
Jaskólski, M
Brzezinski, B
JOURNAL OF MOLECULAR STRUCTURE, 1999, 475 (2-3) : 167 - 173
[29] Crystal chemistry of protonated 1,2-bis(di-R-aminomethyl)benzenes. Part II: 1,2-bis(dimethylaminomethyl)benzene nitrate
Bartoszak-Adamska, E
Jaskolski, M
Brzezinski, B
JOURNAL OF MOLECULAR STRUCTURE, 1998, 448 (01) : 57 - 62
[30] Crystal chemistry of protonated 1,2-bis(di-R-aminomethyl)benzenes.: Part VII:: 1,2-bis(dipropylaminomethyl)benzene perchlorate
Bartoszak-Adamska, E
Jaskólski, M
Urjasz, H
Brzezinski, B
JOURNAL OF MOLECULAR STRUCTURE, 2005, 738 (1-3) : 271 - 274

← 1 2 3 4 5 →