Recent advances on nonenzymatic catalytic kinetic resolution of diols

被引：22
|
作者：
Yang, Hui [1 ]
Zheng, Wen-Hua [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, 163 Xianlin Ave, Nanjing 210023, Jiangsu, Peoples R China
来源：
TETRAHEDRON LETTERS | 2018年 / 59卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Nonenzymatic; Kinetic resolution; Dials; Selectivity; ENANTIOSELECTIVE ACYL TRANSFER; SECONDARY ALCOHOLS; TERMINAL EPOXIDES; ASYMMETRIC DESYMMETRIZATION; OXIDATIVE ESTERIFICATION; RACEMIC MIXTURES; SUBSTRATE SCOPE; 1,2-DIOLS; ACYLATION; TRANS-CYCLOALKANE-1,2-DIOLS;
D O I：
10.1016/j.tetlet.2017.12.080
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
As one of the most efficient and straight-forward strategies for obtaining optically pure compounds, catalytic kinetic resolution has been widely used in laboratory and industry. Although nonenzymatic catalytic kinetic resolution of secondary alcohol has been well developed, it still remains a formidable challenge for kinetic resolution of diols which play a significant role in natural products synthesis. The purpose of this digest is to present the recent progress on nonenzymatic catalytic kinetic resolution of representative dials. (C) 2018 Elsevier Ltd. All rights reserved.
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页码：583 / 591
页数：9
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